4-(Hydroxymethyl)phenol
نویسندگان
چکیده
In the mol-ecule of the title compound, C(7)H(8)O(2), the phenol O and hydroxy-methyl C atoms lie in the ring plane [deviations of -0.015 (3) and and 0.013 (3) Å, respectively]. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link mol-ecules into a network. A weak C-H⋯π inter-action is also found.
منابع مشابه
Low-temperature redetermination of 4-chloro-2-[tris(hydroxymethyl)methyliminomethyl]phenol as zwitterionic 4-chloro-2-[tris(hydroxymethyl)methyliminiomethyl]phenolate
The title Schiff base, C(11)H(14)ClNO(4), originally refined as a neutral mol-ecule [Chumakov, Antosyak, Mazus, Tsapkov & Samus (2000), Crystallogr. Rep.45, 945-950], is inter-preted as a zwitterionic compound. There are two independent zwitterions in the asymmetric unit. Five of the six hydr-oxy groups of the -CH(2)OH fragments are disordered. In one zwitterion, two are disordered over three s...
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The title complex, [Ni(2)(C(4)H(8)N(4)O(2))(6)](NO(3))(4)·2CH(4)O, contains a centrosymmetric binuclear nickel(II) complex bridged by a pair of 4-amino-3,5-bis-(hydroxy-meth-yl)-1,2,4-triazole ligands. The separation between the Ni(II) atoms is 3.962 (1) Å. The Ni atoms are in a slightly distorted octa-hedral coordination. Inter-molecular N-H⋯O, N-H⋯N and O-H⋯O hydrogen bonds connect the ligand...
متن کامل4-Hydroxymethyl-2-methoxyphenol
The title compound, C(8)H(10)O(3), is close to planar (r.m.s. deviation = 0.042 Å) apart from the hydroxyl O atom [deviation = 1.285 (1) Å] and an intra-molecular O-H⋯O hydrogen bond occurs. In the crystal, inter-molecular O-H⋯O links lead to chains propagating in [001].
متن کامل(2S,3R,4R,5R)-3,4-Dihydroxy-5-(hydroxymethyl)pyrrolidine-2-carboxylic acid [(2S,3R,4R,5R)-3,4-dihydroxy-5-(hydroxymethyl)proline]
The crystal structure of the title compound, C(6)H(11)NO(5), establishes the relative configuration at the four stereogenic centres; the absolute configuration is determined by the use of d-glucuronolactone as the starting material for the synthesis. Mol-ecules are linked by inter-molecular O-H⋯O and N-H⋯O hydrogen bonds into a three-dimensional network, with each mol-ecule acting as a donor an...
متن کامل5,5-Bis(hydroxymethyl)-2-phenyl-1,3-dioxane
In the title compound, C(12)H(16)O(4), the 1,3-dioxane ring adopts a chair conformation; the 2-phenyl substitutent occupies an equatorial position. Adjacent mol-ecules are linked by O-H⋯O hydrogen bonds into a chain.
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